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Anomalous Properties

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Which property makes oxygen anomalous in group 16?

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About This Question

Subject
chemistry
Chapter
classification of elements and periodicity in properties
Topic
anomalous properties
Difficulty
Easy
Year
2025
Tags
Anomalous PropertiesOxygenGroup 16

Solution

Correct Answer:

Smallest size and high electronegativity

The first element of any group in the -block (like Oxygen) shows behavior different from other members of its group.

  • Oxygen is anomalous because of:
  1. Extremely Small Size.
  2. High Electronegativity (second only to Fluorine).
  3. Non-availability of valence d-orbitals.
  • This leads to peculiar behaviors such as the ability to form strong hydrogen bonds (unlike ), gas state at STP ( vs ), and a maximum coordination number of 4.

This easy difficulty chemistry question is from the chapter classification of elements and periodicity in properties, covering the topic of anomalous properties. It appeared in the 2025 exam.

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