Alcohols
Easychemistry
The order of reactivity of alcohols with HCl-ZnCl₂ (Lucas reagent) is:
Select the correct option:
Solution
Incorrect! Answer:
3° > 2° > 1°
The Lucas Test distinguishes between primary, secondary, and tertiary alcohols using a mixture of concentrated HCl and anhydrous ZnCl2.
- The reaction follows an SN1 mechanism through a carbocation intermediate.
- Reactivity Order: 3∘ (Tertiary) >2∘ (Secondary) >1∘ (Primary).
- Observation:
- 3∘ Alcohols: Form turbidity (alkyl chloride) immediately.
- 2∘ Alcohols: Form turbidity in 5-10 minutes.
- 1∘ Alcohols: Do not produce turbidity at room temperature; reaction occurs only upon heating.
🔒 Solution Hidden from View
Submit your answer to unlock the detailed step-by-step solution.
About This Question
- Subject
- chemistry
- Chapter
- organic compounds containing oxygen
- Topic
- alcohols
- Difficulty
- Easy
- Year
- 2025
This easy difficulty chemistry question is from the chapter organic compounds containing oxygen, covering the topic of alcohols. It appeared in the 2025 exam. Practice this and similar questions to strengthen your understanding of organic compounds containing oxygen concepts.
Looking for more practice? Explore all chemistry questions or browse organic compounds containing oxygen questions on RankGuru.